Dr. Marius Lutz
Postdoctoral Researcher with Kyoko Nozaki @UTokyo - PhD with Bill Morandi @ETHZ
Dr. Marius Lutz LinkedIn
Dr. Marius Lutz LinkedIn
Dr. Marius Lutz X
Dr. Marius Lutz X
Dr. Marius Lutz Substack
Dr. Marius Lutz Substack
Publications
Mechanistic Investigation of the Rhodium-Catalyzed Transfer Hydroarylation Reaction Involving Reversible C−C Bond Activation (JACS, 2023)
Mechanistic Investigation of the Rhodium-Catalyzed Transfer Hydroarylation Reaction Involving Reversible C−C Bond Activation (JACS, 2023)
Synthesis and Reversible H2 Activation by Coordinatively Unsaturated Rhodium NHC Complexes (HCA, 2023)
Synthesis and Reversible H2 Activation by Coordinatively Unsaturated Rhodium NHC Complexes (HCA, 2023)
Activity-Based Approach for Selective Molecular CO2 Sensing (JACS, 2022)
Activity-Based Approach for Selective Molecular CO2 Sensing (JACS, 2022)
Shuttle arylation by Rh(I) catalyzed reversible carbon–carbon bond activation of unstrained alcohols (Chem, 2021)
Shuttle arylation by Rh(I) catalyzed reversible carbon–carbon bond activation of unstrained alcohols (Chem, 2021)
Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols (Chem. Rev., 2020)
Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols (Chem. Rev., 2020)
The functionalization of molecules by cleaving inert carbon–carbon single bonds is regarded as a great synthetic challenge due to their inherent stability. In recent years, significant progress has been made in the activation of small rings relying on the release of strain energy. By contrast, the number of catalytic methodologies for the activation of unstrained carbon–carbon single bonds is still limited. This review focuses on the recent developments in transition-metal-catalyzed cleavage of C–C bonds in unstrained alcohols via β-carbon elimination. Emphasis is placed on the mechanistic aspects of the discussed transformations and their applications to the deconstruction and reorganization of molecules.
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