Dr. Elliott Denton
Postdoctoral Researcher, Mecking Group, University of Konstanz
Dr. Elliott Denton LinkedIn
Dr. Elliott Denton LinkedIn
Dr. Elliott Denton Email
Dr. Elliott Denton Email
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Postdoctoral Research - Cited by 246 - Organic Chemistry - Catalysis - Polymers
From Lipoic Acid to 1,2-Dithianes: Expanding Radical Ring-Opening to Less-Activated Monomers Such as Vinyl Acetate | Journal of the American Chemical Society
From Lipoic Acid to 1,2-Dithianes: Expanding Radical Ring-Opening to Less-Activated Monomers Such as Vinyl Acetate | Journal of the American Chemical Society
Ligand Design Enables the Palladium-Catalyzed Intermolecular Carbochlorocarbonylation of Alkynes and Cyclopentenone Formation
Ligand Design Enables the Palladium-Catalyzed Intermolecular Carbochlorocarbonylation of Alkynes and Cyclopentenone Formation
The Divergent Reactivity of Acid Chlorides Under Transition Metal Catalysis
The Divergent Reactivity of Acid Chlorides Under Transition Metal Catalysis
Modular Access to Bifunctional Norbornenes and Their Application in Ring-Opening Metathesis Polymerization
Modular Access to Bifunctional Norbornenes and Their Application in Ring-Opening Metathesis Polymerization
Intermolecular Pauson-Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate
Intermolecular Pauson-Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate
Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C−COCl Bond Cleavage
Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C−COCl Bond Cleavage
Palladium-catalysed carboformylation of alkynes using acid chlorides as a dual carbon monoxide and carbon source
Palladium-catalysed carboformylation of alkynes using acid chlorides as a dual carbon monoxide and carbon source
In an effort to extend the important hydroformylation reaction, a palladium-catalysed carboformylation reaction has now been developed in which two new carbon–carbon bonds are created across an alkyne. This modular reaction relies on a CO shuffling process and uses an acid chloride as a dual carbon and CO source.
Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid Chlorides and Alkynes
Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid Chlorides and Alkynes
We describe a general strategy for the intermolecular synthesis of polysubstituted cyclopentenones using palladium catalysis. Overall, this reaction is achieved via a molecular shuffling process involving an alkyne, an α,β-unsaturated acid chloride, which serves as both the alkene and carbon monoxide source, and a hydrosilane to create three new C–C bonds. This new carbon monoxide-free pathway delivers the products with excellent yields. Furthermore, the regioselectivity is complementary to conventional methods for cyclopentenone synthesis. In addition, a set of regio- and chemodivergent reactions are presented to emphasize the synthetic potential of this novel strategy.
Difunctionalization of C–C σ-Bonds Enabled by the Reaction of Bicyclo[1.1.0]butyl Boronate Complexes with Electrophiles: Reaction Development, Scope, and Stereochemical Origins
Difunctionalization of C–C σ-Bonds Enabled by the Reaction of Bicyclo[1.1.0]butyl Boronate Complexes with Electrophiles: Reaction Development, Scope, and Stereochemical Origins
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